201601

LiFePO4/C 复合材料的合成及其电化学性能
发布人:网站管理员 发布时间:2016/1/8 点击次数:201次
  

LiFePO4/C 复合材料的合成及其电化学性能
曹敦俊1,马迪辉1,陈晗2
(1. 株洲市第二中学,湖南株洲412000;2. 湖南工业大学,湖南株洲412011)
摘要: 采用柳絮为碳源和模板,通过蒸发自组装合成LiFePO4/C复合材料。柳絮的添加量对复合材料的形貌影响较明
显,当柳絮添加量为5%时,材料的形貌完整,柳絮碳上均匀覆盖着LiFePO4纳米线。复合材料在0.1C倍率下放电比容量最
高,为141 mA·h/g,倍率为1C时,放电容量达到130 mA·h/g以上,循环600周后,容量保持率在95%以上。
关键词: 锂离子电池;LiFePO4;复合材料;电化学性能
中图分类号: TM912 文献标识码: A 文章编号: 2095-0802-(2016)01-0081-02
Preparation and Electrochemical Performance of LiFePO4 /C Composite
CAO Dunjun1,MA Dihui2,CHEN Han2
(1. No. 2 Middle School of Zhuzhou, Zhuzhou 412000, Hunan, China;2. Hunan University of Technology, Zhuzhou 412011,
Hunan, China)
Abstract: LiFePO4/C composites were synthesized by evaporative self-assembly using catkins as carbon source and template. The
adding quantity of catkins in composite material has an obvious influence on their morphology. When 5% catkins are applied, the
composite material exhibits perfect morphology, and catkin carbon is evenly covered by LiFePO4 nanowires. The composite
delivers the highest discharge capacity of 141 mA·h/g at 0.1C rate, the discharge capacity under 1 C rate reaches 130 mA·h/g,
the capacity retention was above 95% after 600 cycles.

Key words: lithium ion batteries; LiFePO4; composite materials; electrochemical performance